Process Design for Size-Controlled Flame Spray Synthesis of Li4Ti5O12 and Electrochemical Performance

Journal title

Chemical and Process Engineering




vol. 38


No 1



Li-ion battery ; Li4Ti5O12 ; size control ; residence time distribution ; computational fluid dynamics ; flame synthesis of electroceramics

Divisions of PAS

Nauki Techniczne




Polish Academy of Sciences Committee of Chemical and Process Engineering




Artykuły / Articles


DOI: 10.1515/cpe-2017-0005 ; ISSN 0208-6425


Chemical and Process Engineering; 2017; vol. 38; No 1; 51-66


Wagemaker (2009), Li - ion diffusion in the equilibrium nanomorphology of spinel xTi, Phys Chem B, 4, 113, ; Waser (2014), Air entrainment during flame aerosol synthesis of nanoparticles, Aerosol Sci Technol, 48, ; Pratsinis (1998), Flame aerosol synthesis of ceramic powders, Prog Energ Combust, 24, ; Naoi (2013), New generation nanohybrid supercapacitor ", Accounts Chem Res, 46, ; Kho (2011), Dopant - free , polymorphic design of TiO nanocrystals by flame aerosol synthesis, Chem Eng Sci, 66, ; Gaberscek (2007), Is small particle size more important than carbon coating ? An example study on LiFePO cathodes, Electrochem Commun, 9, 4, ; Poullikkas (2013), A comparative overview of large - scale battery systems for electricity storage, Renew Sust Energ Rev, 27, ; Athanassiou (2006), Large - scale production of carbon - coated copper nanoparticles for sensor applications, Nanotechnology, 17, ; Vlad (2014), Hybrid supercapacitor - battery materials for fast electrochemical charge storage, Sci Rep, 4, 1, ; Teleki (2006), Sensing of organic vapors by flame - made TiO nanoparticles, Chem, 119, ; Mueller (2004), Non - agglomerated dry silica nanoparticles, Powder Technol, 140,\ ; Karhunen (2011), Transition metal - doped lithium titanium oxide nanoparticles made using flame spray pyrolysis, ISRN Nanotechnology, 2011, ; Hudak (2012), Size effects in the electrochemical alloying and cycling of electrodeposited aluminum with lithium, Electrochem Soc, 159, ; Deschanvres (1971), Synthesis and crystallographic study of new solid solution of spinelle xTi - xO less than or equal to x less than or equal to, Mater Res Bull, 1, 4, ; Teoh (2010), Flame spray pyrolysis : An enabling technology for nanoparticles design and fabrication, Nanoscale, 2, 1324, ; Ohzuku (1995), Zero - strain insertion material of Li ti for rechargeable lithium cells, Electrochem Soc, 1, 142, ; Jiang (2004), Comparison of the reactions between Ti or LiC and nonaqueous solvents or electrolytes using accelerating rate calorimetry, Electrochem Soc, 7, 151, ; Du Pasquier (2009), Nano Ti - LiMn batteries with high power capability and improved cycle - life, Power Sources, 4, 186, ; Wegner (2003), Scale - up of nanoparticle synthesis in diffusion flame reactors, Chem Eng Sci, 58, ; Groehn (2012), Fluid - particle dynamics during combustion spray aerosol synthesis of ZrO, Chem Eng J, 191, ; Johannessen (2000), Computational fluid - particle dynamics for the flame synthesis of alumina particles, Chem Eng ci, 55, ; Waser (2011), Continuous flame aerosol synthesis of carbon - coated nano - LiFePO for Li - ion batteries, Aerosol Sci, 4, 42, ; Ernst (2007), Electrochemically active flame - made nanosized spinels : LiMn Ti and LiFe, Mater Chem Phys, 4, 4, ; Armand (2008), Building better batteries, Nature, 451, ; Mueller (2003), Nanoparticle synthesis at high production rates by flame spray pyrolysis, Chem Eng Sci, 58, ; Sotiriou (2010), Non - toxic dry - coated nanosilver for plasmonic biosensors, Adv Funct Mater, 20, ; Curtet (1958), Confined jets and recirculation phenomena with cold air, Combust Flame, 2, ; Padhi (1997), Phospho - olivines as positive - electrode materials for rechargeable lithium batteries, Electrochem Soc, 144, ; Olfe (1961), Mean beam length calculations for radiation from non - transparent gases, Quant Spectrosc Ra, 1, ; Teleki (2008), In situ coating of flame - made TiO particles with nanothin SiO films, Langmuir, 24, ; Gamba (2012), Residence time distribution determination of a continuous stirred tank reactor using computational fluid dynamics and its application on the mathematical modeling of styrene polymerization, Int J Chem React Eng, 10, 1, ; Magnussen (1977), On mathematical modeling of turbulent combustion with special emphasis on soot formation and combustion, Symp Int Combust, 16, 719, ; Madler (2002), Controlled synthesis of nanostructured particles by flame spray pyrolysis, Aerosol Sci, 33, ; Krumeich (null), Thermal annealing dynamics of carbon - coated LiFePO nanoparticles studied by in - situ analysis State, Solid Chem, 2016, ; Hsiao (2008), Microstructure effect on the electrochemical property of Ti as an anode material for lithium - ion batteries, Electrochim Acta, 4, 53, ; Groehn (2014), Scale - up of nanoparticle synthesis by flame spray pyrolysis : The high - temperature particle residence time, Ind Eng Chem Res, 53, ; Birozzi (2015), von Passerini Scaling up Ti for high - power lithium - ion anodes using large flame spray pyrolysis, nano Electrochem Soc, 4, 162, ; Rudin (2011), Uniform nanoparticles by flame - assisted spray pyrolysis FASP of low cost precursors, Nanopart Res, 13, ; Streltsov (1993), Multipole analysis of the electron - density in triphylite using ray - diffraction data, Acta Crystallogr B, 4, 49, ; Strobel (2007), Flame aerosol synthesis of smart nanostructured materials, Mater Chem, 17, 4743, ; Laruelle (2002), On the origin of the extra electrochemical capacity displayed by MO / Li cells at low potential, Electrochem Soc, 149, ; Bresser (2012), The importance of going nano for high power battery materials, Power Sources, 219, ; Morrison (1997), In situ Fourier transform infrared characterization of the effect of electrical fields on the flame synthesis of TiO particles, Chem Mater, 9, 2702, ; Madler (2002), Flame - made ceria nanoparticles, Mater Res, 17, ; Kavan (2003), Li insertion into Ti - Charge capability vs particle size in thin - film electrodes, Electrochem Soc, 4, 150, ; Asbrink (1970), A refinement of crystal structure of copper ( oxide with a discussion of some exceptional s Acta Crystall, B Stru, 26, 8. ; Strobel (2009), Direct synthesis of maghemite , magnetite and wustite nanoparticles by flame spray pyrolysis, Adv Powder Technol, 20, ; Zheng (2012), A comprehensive understanding of electrode thickness effects on the electrochemical performances of Li - ion battery cathodes, Electrochim Acta, 71, ; Waser (2013), Size controlled CuO nanoparticles for Li - ion batteries, Power Sources, 241,

Editorial Board

Editorial Board

Ali Mesbach, UC Berkeley, USA

Anna Gancarczyk, Institute of Chemical Engineering, Polish Academy of Sciences, Poland

Anna Trusek, Wrocław University of Science and Technology, Poland

Bettina Muster-Slawitsch, AAE Intec, Austria

Daria Camilla Boffito, Polytechnique Montreal, Canada

Donata Konopacka-Łyskawa, Gdańsk University of Technology, Poland

Dorota Antos, Rzeszów University of Technology, Poland

Evgeny Rebrov, University of Warwick, UK

Georgios Stefanidis, National Technical University of Athens, Greece

Ireneusz Grubecki, Bydgoszcz Univeristy of Science and Technology, Poland

Johan Tinge, Fibrant B.V., The Netherlands

Katarzyna Bizon, Cracow University of Technology, Poland

Katarzyna Szymańska, Silesian University of Technology, Poland

Marcin Bizukojć, Łódź University of Technology, Poland

Marek Ochowiak, Poznań University of Technology, Poland

Mirko Skiborowski, Hamburg University of Technology, Germany

Nikola Nikacevic, University of Belgrade, Serbia

Rafał Rakoczy, West Pomeranian University of Technology, Poland

Richard Lakerveld, Hong Kong University of Science and Technology, Hong Kong

Tom van Gerven, KU Leuven, Belgium

Tomasz Sosnowski, Warsaw University of Technology, Poland